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Peculiarities of dielectric properties of proton conducting (K$_{0.3}$(NH$_{4}$)$_{0.7}$)$_3$H(SO$_4$)$_2$ single crystals (to discussion of negative dielectric permittivity)

N. D. Gavrilova$^1$, I. A. Malyshkina$^1$, V. K. Novik$^2$, E. V. Selezneva$^3$, I. P. Makarova$^3$

Memoirs of the Faculty of Physics 2017. N 4.

  • Article
Annotation

On the example of superprotonic crystal (K$_{0.3}$(NH$_{4}$)$_{0.7}$)$_3$H(SO$_4$)$_2$, a first attempt was made to detect, by means of dielectric investigations, the presence of structure elements in the material, which are devoid of elastic bonds or having loosen bonds with crystal matrix. It was shown that it is possible to separate contributions from structure elements with elastic bonds, which are devoid of elastic bonds or having loosen bonds in comparison with influence of measuring field. A supposition was stated about sequence of physical mechanisms which determine the reaction of quasi-free structure elements on the growth of measuring field.

Received: 2017 June 21
Approved: 2017 July 25
PACS:
77.22.-d Dielectric properties of solids and liquids
77.84.-s Dielectric, piezoelectric, ferroelectric, and antiferroelectric materials
Authors
N. D. Gavrilova$^1$, I. A. Malyshkina$^1$, V. K. Novik$^2$, E. V. Selezneva$^3$, I. P. Makarova$^3$
$^1$Faculty of physics, Lomonosov Moscow State University, chair of Physics of Polymers and Crystals.\
$^2$Department of Theoretical Physics, Faculty of physics, Lomonosov Moscow State University, chair of General Physics and Wave Processes.\
$^3$FSRC “Crystallography and Photonics” of RAS
Issue 4, 2017

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